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Quality Requirements Edition 5.0                                                                                  European Enamel Association






            8.7.3       Valuation of cracks in enamellings                             The  formation  of cracks,  as  a result  of a too  long  and  unreasonable  influence  of high
                                                                                       temperature,  (e.g.  more  than  530  C) often  displays  a metallic  luster  as a result  of the
                                                                                                                   0

            Definition  and  cause                                                     diffusion of metal oxide.
            Following the definition of DIN 50903: Cracks are mostly laminar interruptions in enamel-
            lings. They often run vertical to the surface, but occur also under different angles. Their  Test report
            causes are mainly mechanical - or thermal tensions in the compound system.   In the test report to be mentioned:
            Under thermal shocks, tensile stresses are built up due to different expansion behaviours   kind and origin of the piece
            of the  metal  substrate  and  the  enamel  to which  an  enamelling  is less  resistant  as to   place and date of testing
            compressive  stresses.  Unreasonable  deformations  or  impact  stresses  on  finished   description of defects, number and extent.

            enamellings set off cracks.


            Consideration and description
            The judgement of damage by cracks is performed by naked eye. One differentiates  be-
            tween:
                a.   open, piercing cracks
                b.   open, non-piercing cracks
                c.   masked cracks


            Open, piercing cracks are interruptions in the enamel layer down to the metal substrate.
            They  can be made  visible  clearly  by physical  (e.g.  electrostatic)  or chemical  methods.
            Open, non-piercing cracks cease in the enamel layer. They cannot be made visible by such
            method, as there is no prerequisite reaction with the metal substrate. Wet or dry pigments

            are rubbed into the enamel surface, in order  to recognize such crack formation. These   Illustration: Formation of cracks in an enamel layer (enlargement 200 : 1)
            pigments  concentrate  on the edges  of cracks,  by which  they clearly  indicate  the crack
            propagation.


            Masked (inner) cracks glimmer in the enamel layer like mother-of-pearl, dependent on the
            lighting equipment and lighting angle.







            © EEA2020                                                                                                                                 page 123
               EEA2020
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