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Quality Requirements Edition 6.0                                                                                  European Enamel Association




            8.7.2    Valuation of burn-off on enamellings                              As a result of the firing process, high amounts of iron oxide withdraw the opacifying TiO2
                                                                                       from the enamel layer, due to the formation of iron Titanate (needle like crystals). The
            Definition and cause                                                       covering  power  in  the  defect  area  is  reduced  -  as  a  black  line  is  formed  (optical
                                                                                       impairment). In the reach of burnings, corrosive stressed articles do not have a complete
            Burn-offs or burnings are locally limited defects, caused by a too thin applied enamel
                                                                                       protection against corrosion. Therefore, burnings are to be bound by perfect processed
            coating. Due to an excessive oxidation of the metal substrate by firing, the enamel
                                                                                       cutting edges and welding seams.
            coat could not form a regular stratified structure or it has been destroyed by a super

            saturation of metal oxides.                                                Consideration and description
                                                                                       The judgement of the linear extension of burnings is performed by naked eye and, as
            Typical  burnings  occur  on  cutting  edges  or  in  the  reach  of  welding  seams.  The   agreed upon, to be measured out. The dimension of the destroyed surface is to be
            thickness of the destroyed enamel layer is not measurable with customary types of   expressed in cm .
                                                                                                    2
            measuring  instruments  complying  to  EN  ISO  2178.  The  determination  has  to  be
            carried out on cross sections with the help of a light-microscope.         On difficult accessible containers, equipped with protecting anodes, a measurement of
                                                                                       the protective current requirement can be an indication for the extent of burnings.
            The illustrations (Enlargement 50 : 1 resp. 500 : 1) display the result of a poor cutting
            edge with a direct-on white enamelling.                                    Test report

                                                                                       To be mentioned in the test report:
                                                                                          kind and origin of the test piece
                                                                                          place and date of the testing
                                                                                          description of defects, number and extent
                                                                                          location of defects on the enamelled article














            Direct-on white enamelling               Direct-on white enamelling
            on a squeezed-off edge (50 : 1)          on a squeezed-off edge (500 : 1)



            © EEA2025                                                                                                                                 page 125
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